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Categories: Chemistry: Biochemistry, Physics: Quantum Physics

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Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. A team has now analyzed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

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An international research team has succeeded in controlling the chirality of individual molecules through structural isomerization. The team also succeeded in synthesizing highly reactive diradicals with two unpaired electrons. These achievements were made using a scanning tunneling microscope probe at low temperatures.

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Lithium-sulfur batteries have exceptional theoretical capacity and performance in combination with an element in abundant supply. But the intricate reaction mechanism, particularly during discharge, has been challenging to solve. Researchers have identified the key pathways to a complex sulfur reduction reaction that leads to energy loss and reduced battery life span. The study's findings establish the whole reaction network for the first time and offer insight into electrocatalyst design for improved batteries.

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In hydrogen fuel cells, electrolyte membranes frequently undergo deformation and develop cracks during operation. A research team has recently introduced a fatigue-resistant polymer electrolyte membrane for hydrogen fuel cells, employing an interpenetrating network of Nafion (a plastic electrolyte) and perfluoropolyether (a rubbery polymer). This innovation will not only improve fuel cell vehicles but also promises advancements in diverse technologies beyond transportation, spanning applications from drones to desalination filters and backup power sources.

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Researchers have developed a new biocontainment method for limiting the escape of genetically engineered organisms used in industrial processes.

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A crystals expert has published an answer to how crystals are formed and how molecules become a part of them, solving an age-old mystery about crystal formation.

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Scientists have found a way to boost ethanol production via yeast fermentation, a standard method for converting plant sugars into biofuels. Their approach relies on careful timing and a tight division of labor among synthetic yeast strains to yield more ethanol per unit of plant sugars than previous approaches have achieved.

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Scientists have found soundwaves from low-intensity focused ultrasound aimed at a place deep in the brain called the insula can reduce both the perception of pain and other effects of pain, such as heart rate changes.

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Researchers have developed a first-of-its-kind, handheld electrochemical sensor that can accurately detect fentanyl in urine within seconds. The proof-of-concept technology can detect even trace amounts of fentanyl with 98% accuracy using a small portable device without costly and time-consuming lab analysis.

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Engineers have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous technologies.

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Scientists have used a combination of scanning transmission electron microscopy (STEM) and computational modeling to get a closer look and deeper understanding of tantalum oxide. When this amorphous oxide layer forms on the surface of tantalum -- a superconductor that shows great promise for making the 'qubit' building blocks of a quantum computer -- it can impede the material's ability to retain quantum information. Learning how the oxide forms may offer clues as to why this happens -- and potentially point to ways to prevent quantum coherence loss.

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Scientists have discovered that adding a layer of magnesium improves the properties of tantalum, a superconducting material that shows great promise for building qubits, the basis of quantum computers. The scientists show that a thin layer of magnesium keeps tantalum from oxidizing, improves its purity, and raises the temperature at which it operates as a superconductor. All three may increase tantalum's ability to hold onto quantum information in qubits.

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Researchers have succeeded in generating a logical qubit from a single light pulse that has the inherent capacity to correct errors.

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Scientists developed a new method to map exactly how a fungus works with leafcutter ants in a complex microbial community to degrade plant material at the molecular level. The team's insights are important for biofuels development.

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It's an achievement with important implications for scientists studying the brain and working on treatments for a broad range of neurological and neurodevelopmental disorders, such as Alzheimer's and Parkinson's disease.

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Researchers demonstrated a 300 GHz-band wireless link that was able to transmit data over a single channel at a rate of 240 gigabits per second. The wireless communication system employs signal generators based on lasers that have ultra-low phase noise in the sub-terahertz band. This rate is the highest so far reported at these frequencies and is a substantial step forward in 300 GHz-band communications for 6G networks.

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Researchers recently succeeded in producing a highly durable time crystal that lived millions of times longer than could be shown in previous experiments. By doing so, they have corroborated an extremely interesting phenomenon that Nobel Prize laureate Frank Wilczek postulated around ten years ago and which had already found its way into science fiction movies.

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Researchers have developed a transmissive thin scintillator using perovskite nanocrystals, designed for real-time tracking and counting of single protons. The exceptional sensitivity is attributed to biexcitonic radiative emission generated through proton-induced upconversion and impact ionization.

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Researchers have gained new insights into the development of the light-induced ferroelectric state in SrTiO3. They exposed the material to mid-infrared and terahertz frequency laser pulses and found that the fluctuations of its atomic positions are reduced under these conditions. This may explain why the dipolar structure is more ordered than in equilibrium and why the laser pulses induce a ferroelectric state in the material.

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A team of researchers mapped out how flecks of 2D materials move in liquid -- knowledge that could help scientists assemble macroscopic-scale materials with the same useful properties as their 2D counterparts.