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Categories: Chemistry: Inorganic Chemistry, Computer Science: Artificial Intelligence (AI)

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Nearly 30 years ago, scientists discovered a unique class of anticancer molecules in a family of bryozoans, a phylum of marine invertebrates found in tropical waters. The chemical structures of these molecules, which consist of a dense, highly complex knot of oxidized rings and nitrogen atoms, has attracted the interest of organic chemists worldwide, who aimed to recreate these structures from scratch in the laboratory. However, despite considerable effort, it has remained an elusive task. Until now, that is. A team of chemists has succeeded in synthesizing eight of the compounds for the first time using an approach that combines inventive chemical strategy with the latest technology in small molecule structure determination.

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Whether ultramarine, cerulean, Egyptian or cobalt, blue pigments have colored artworks for centuries. Now, seemingly out of the blue, scientists have discovered a new blue pigment that uses less cobalt but still maintains a brilliant shine. Though something like this might only happen once in a blue moon, the cobalt-doped barium aluminosilicate colorant withstands the high temperatures found in a kiln and provides a bright color to glazed tiles.

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Graphene is an enormously promising material. It consists of a single layer of carbon atoms arranged in a honeycomb pattern and has extraordinary properties: exceptional mechanical strength, flexibility, transparency and outstanding thermal and electrical conductivity. If the already two-dimensional material is spatially restricted even more, for example into a narrow ribbon, controllable quantum effects can be created. This could enable a wide range of applications, from vehicle construction and energy storage to quantum computing.

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Scientists introduce what they call 'simultaneous and heterogeneous multithreading' or SHMT. This system doubles computer processing speeds with existing hardware by simultaneously using graphics processing units (GPUs), hardware accelerators for artificial intelligence (AI) and machine learning (ML), or digital signal processing units to process information.

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Reduce, reuse, recycle, and repurpose: These are all ways we can live more sustainably. One tricky aspect of recycling, though, is that sometimes the recycling process is chemically intensive, and this is the case for recycling one of the world's most abundant materials -- chitin. Researchers have tackled this problem and found a way to sustainably recover chitin from seafood waste.

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A research team has unveiled a novel ligand exchange technique that enables the synthesis of organic cation-based perovskite quantum dots (PQDs), ensuring exceptional stability while suppressing internal defects in the photoactive layer of solar cells.

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Biomolecules such as amino acids and sugars occur in two mirror-image forms -- in all living organisms, however, only one is ever found. Why this is the case is still unclear. Researchers have now found evidence that the interplay between electric and magnetic fields could be at the origin of this phenomenon.

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Physicists have used complex computer simulations to develop a new design for significantly more efficient solar cells than previously available. A thin layer of organic material, known as tetracene, is responsible for the increase in efficiency.

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Single-molecule magnets (SMMs) are exciting materials. In a recent breakthrough, researchers have used deep learning to predict SMMs from 20,000 metal complexes. The predictions were made solely based on the crystal structures of these metal complexes, thus eliminating the need for time-consuming experiments and complex simulations. As a result, this method is expected to accelerate the development of functional materials, especially for high-density memory and quantum computing devices.

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Polystyrene is a widespread plastic that is essentially not recyclable when mixed with other materials and is not biodegradable. A research team has now introduced a biohybrid catalyst that oxidizes polystyrene microparticles to facilitate their subsequent degradation. The catalyst consists of a specially constructed 'anchor peptide' that adheres to polystyrene surfaces and a cobalt complex that oxidizes polystyrene.

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Researchers reported finding microplastics in all 62 of the placenta samples tested, with concentrations ranging from 6.5 to 790 micrograms per gram of tissue.

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Hydrogels are already used in clinical practice for the delivery of drugs, and as lenses, bone cement, wound dressings, 3D scaffolds in tissue engineering and other applications. However, bonding different hydrogel polymers to one another has remained a challenge; yet it could enable numerous new applications. Now, researchers have pioneered a new method that uses a thin film of chitosan, a fibrous sugar-based material derived from the processed outer skeletons of shellfish, to make different hydrogels instantaneously and strongly stick to each other. They used their approach to locally protect and cool tissues, seal vascular injuries, and prevent unwanted 'surgical adhesions' of internal body surfaces.

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Researchers have discovered a solid material that rapidly conducts lithium ions. Consisting of non-toxic earth-abundant elements, the new material has high enough Li ion conductivity to replace the liquid electrolytes in current Li ion battery technology, improving safety and energy capacity. The research team have synthesized the material in the laboratory, determined its structure and demonstrated it in a battery cell.

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Scientists report the first look at electrons moving in real-time in liquid water; the findings open up a whole new field of experimental physics.

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A simple new technique could boost the efficiency of some key chemical processing, by up to a factor of 100,000, researchers report. The reactions are at the heart of petrochemical processing, pharmaceutical manufacturing, and many other industrial chemical processes.

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Since the turn of the century, six new chemical elements have been discovered and subsequently added to the periodic table of elements, the very icon of chemistry. These new elements have high atomic numbers up to 118 and are significantly heavier than uranium, the element with the highest atomic number (92) found in larger quantities on Earth. This raises questions such as how many more of these superheavy species are waiting to be discovered, where -- if at all -- is a fundamental limit in the creation of these elements, and what are the characteristics of the so-called island of enhanced stability. In a recent review, experts in theoretical and experimental chemistry and physics of the heaviest elements and their nuclei summarize the major challenges and offer a fresh view on new superheavy elements and the limit of the periodic table.

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The properties of supramolecular polymers are dictated by the self-assembled state of the molecules. However, not much is known about the impact of morphologies on the properties of nano- and mesoscopic-scale polymeric assemblies. Recently, a research team demonstrated how terminus-free toroids and random coils derived from the same luminescent molecule show different photophysical properties. The team also presented a novel method for purifying the toroidal structure.

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You can mend a broken heart this valentine s day now that researchers invented a new hydrogel that can be used to heal damaged heart tissue and improve cancer treatments.

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Fossils of a marine animal that lived 500 million years ago, combined with computer simulations, informed the design of a new soft robot.

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Scientists have discovered that a known practice in information technology can also be applied to chemistry. Researchers found that to enhance the sampling in chemical simulations, all you need to do is stop and restart.