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Categories: Chemistry: Inorganic Chemistry, Computer Science: Artificial Intelligence (AI)

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Chemists have extended a powerful molecule-building method -- called C-H activation -- to the broad class of chemicals known as alcohols.

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Pumping liquids may seem like a solved problem but optimizing the process is still an area of active research. Any pumping application -- from industrial scales to heating systems at home -- would benefit from a reduction in energy demands. Researchers now showed how pulsed pumping can reduce both friction from and energy consumption of pumping. For this, they took inspiration from a pumping system intimately familiar to everyone: the human heart.

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Beyond-silicon technology demands ultra-high-performance field-effect transistors (FETs). Transition metal dichalcogenides (TMDs) provide an ideal material platform, but the device performances such as contact resistance, on/off ratio, and mobility are often limited by the presence of interfacial residues caused by transfer procedures. We show an ideal residue-free transfer approach using polypropylene carbonate (PPC) with a negligible residue for monolayer MoS2. By incorporating bismuth semimetal contact with atomically clean monolayer MoS2-FET on h-BN substrate, we obtain an ultralow Ohmic contact resistance approaching the quantum limit and a record-high on/off ratio of ~1011 at 15 K. Such an ultraclean fabrication approach could be the ideal platform for high-performance electrical devices using large-area semiconducting TMDs.

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Digital information exchange can be safer, cheaper and more environmentally friendly with the help of a new type of random number generator for encryption. The researchers behind the study believe that the new technology paves the way for a new type of quantum communication.

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Hydrogen spillover is exactly what it sounds like. Small metal nanoparticles anchored on a thermally stable oxide, like silica, comprise a major class of catalysts, which are substances used to accelerate chemical reactions without being consumed themselves. The catalytic reaction usually occurs on the reactive -- and expensive -- metal, but on some catalysts, hydrogen atom-like equivalents literally spill from the metal to the oxide. These hydrogen-on-oxide species are called 'hydrogen spillover.'

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Researchers have revealed an innovative approach to track individual molecule dynamics within nanofluidic structures, illuminating their response to molecules in ways never before possible.

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An artificial intelligence with the ability to look inward and fine tune its own neural network performs better when it chooses diversity over lack of diversity, a new study finds. The resulting diverse neural networks were particularly effective at solving complex tasks.

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A main crux of neuroscience is learning how our senses translate light into sight, sound into hearing, food into taste, and texture into touch. Smell is where these sensory relationships get more complex and perplexing. To address this question, a research team are investigating how airborne chemicals connect to odor perception in the brain. They discovered that a machine-learning model has achieved human-level proficiency at describing, in words, what chemicals smell like.

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The day when robots can cook dinner, clear the kitchen table and empty the dishwasher is still a long way off. First, robots need to be able to recognize the many items of different sizes, shapes and brands in our homes. A team has now made a significant advance toward that technology with a robotic system that uses artificial intelligence to help robots better identify and remember objects.

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By controlling the arrangement of multiple inorganic and organic layers within crystals using a novel technique, researchers have shown they can control the energy levels of electrons and holes (positive charge carriers) within a class of materials called perovskites. This tuning influences the materials' optoelectronic properties and their ability to emit light of specific energies, demonstrated by their ability to function as a source of lasers.

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A team of researchers addressed the question: what happens to a Ga-promoted Cu surface under reaction conditions required for the synthesis of methanol? They found complex structural transformations of this bimetallic catalyst that might change the common view on the catalytically active surface structure.

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Researchers have been able to substantially improve photoclick chemistry. They were able to boost the reactivity of the photoclick compound in the popular PQ-ERA reaction through strategic molecular substitution. They now report a superb photoreaction quantum yield, high reaction rates and notable oxygen tolerance.

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Machine learning model provides quick method for determining the composition of solid chemical mixtures using only photographs of the sample.

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Imagine a robot that can wedge itself through the cracks in rubble to search for survivors trapped in the wreckage of a collapsed building. Engineers are working toward to that goal with CLARI, short for Compliant Legged Articulated Robotic Insect.

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Researchers have developed a miniature battery that could be used to power tiny devices integrated into human tissues. The design uses an ionic gradient across a chain of droplets -- inspired by how electric eels generate electricity. The device was able to regulate the biological activity of human neurons. This could open the way to the development of tiny bio-integrated devices, with a range of applications in biology and medicine.

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A research team overcomes limitations of conventional strain sensors using computer vision integrated optical sensors.

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An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.

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Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.

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Researchers have implemented a quantum-based method to observe a quantum effect in the way light-absorbing molecules interact with incoming photons. Known as a conical intersection, the effect puts limitations on the paths molecules can take to change between different configurations. The observation method makes use of a quantum simulator, developed from research in quantum computing, and offers an example of how advances in quantum computing are being used to investigate fundamental science.

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Researchers have succeeded in transforming brain signals into audible speech. By decoding signals from the brain through a combination of implants and AI, they were able to predict the words people wanted to say with an accuracy of 92 to 100%.