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Categories: Chemistry: Inorganic Chemistry, Mathematics: General

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Because metal-organic frameworks (MOFs) — highly porous metal complexes — are so structurally and chemically diverse, they could be used for many applications, such as drug delivery and environmental clean-up. But researchers still need to get a better understanding of how they function, especially when embedded in polymers. Researchers have now developed and characterized nitric oxide (NO)-storing MOFs embedded in a thin film with novel antibacterial potential.

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Researchers have synthesized a zinc complex based on two zinc centers that absorbs visible light. They demonstrated that this capability depends on the proximity of the zinc ions, where the complex responds to visible light when the zinc atoms are closer. This new property is expected to expand the utility of zinc, which already offers advantages including biological relevance, cost effectiveness, and low toxicity.

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An international team of researchers has published the first harmonized exposure protocol for ecotoxicity testing of microplastics and nanoplastics.

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The interaction between solid matter and positron (the antiparticle of electron) has provided important insights across a variety of disciplines, including atomic physics, materials science, elementary particle physics, and medicine. However, the experimental generation of positronic compounds by bombardment of positrons onto surfaces has proved challenging. In a new study, researchers detect molecular ion desorption from the surface of an ionic crystal when bombarded with positrons and propose a model based on positronic compound generation to explain their results.

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Settling a half century of debate, researchers have discovered that tiny linear defects can propagate through a material faster than sound waves do. These linear defects, or dislocations, are what give metals their strength and workability, but they can also make materials fail catastrophically ­– which is what happens every time you pop the pull tab on a can of soda. The fact that they can travel so fast gives scientists a new appreciation of the unusual types of damage they might do to a broad range of materials in extreme conditions.

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Physicists have experimentally detected how so-called Hubbard excitons form in real-time. 

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Some of the thinnest materials known to humankind -- MXene and MBene compounds -- may provide solutions to scientists in their quest to curb the effects of global warming. These substances are only a few atoms thick, making them two-dimensional. Because of their large surface area, the materials have the potential to absorb carbon dioxide molecules from the atmosphere, which could help reduce the harmful effects of climate change by safely sequestering carbon dioxide, according to a review study.

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An international team of researchers has developed a new theoretical framework that bridges physics and biology to provide a unified approach for understanding how complexity and evolution emerge in nature. This new work on 'Assembly Theory' represents a major advance in our fundamental comprehension of biological evolution and how it is governed by the physical laws of the universe.

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Applying machine learning to find the properties of atomic pieces of geometry shows how AI has the power to accelerate discoveries in maths.

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Researchers have developed a molecular-sized, more efficient version of a widely used electronic sensor, in a breakthrough that could bring widespread benefits.

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Scientists have characterized the genome of a metal-loving bacteria with an affinity for rare earth elements. The research paves the way towards replacing the harsh chemical processing of these elements with a benign practice called biosorption.

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A research team has provided irrefutable proof that certain spherical vortices exist in a stable state.

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Concave, umbrella-like metal complexes provide space to enable the largest molecular rotor operational in the solid-state.

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The behavior of electrons in liquids is crucial to understanding many chemical processes that occur in our world. Using advanced lasers that operate at the attosecond, a team of international researchers has revealed further insights into how electrons behave in liquids.

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The friction on a graphene surface can be dynamically tuned using external electric fields, according to researchers.

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Researchers have developed plasmonic plastic -- a type of composite material with unique optical properties that can be 3D-printed. This research has now resulted in 3D-printed optical hydrogen sensors that could play an important role in the transition to green energy and industry.

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Newly developed ompounds aim to reveal the dual nature of formaldehyde, a chemical that is known to cause cancer but is also believed to play important roles in our biology.

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Chemical engineers have designed a fuel that ignites only with the application of electric current. Since it doesn't react to flames and cannot start accidental fires during storage or transport, it is a 'safe' liquid fuel.

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Humanity continuously emits greenhouse gases and thereby worsens global warming. Increasing research efforts go into developing strategies to convert these gases, such as carbon dioxide (CO2), into valuable products. CO2 accumulates dramatically over the years and is chemically very stable, thus challenging to transform. Yet, for billions of years, some microbes have actively captured CO2 using highly efficient enzymes. Scientists have now isolated one of these enzymes. When the enzyme was electronically branched on an electrode, they observed the conversion of CO2 to formate with perfect efficiency. This phenomenon will inspire new CO2-fixation systems because of its remarkable directionality and rates.

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Scientists have demonstrated 'multielement ink' -- the first 'high-entropy' semiconductor that can be processed at low-temperature or room temperature. The new material could enable cost-effective and energy-efficient semiconductor manufacturing.