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Categories: Chemistry: Inorganic Chemistry, Ecology: Trees

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Researchers have been able to substantially improve photoclick chemistry. They were able to boost the reactivity of the photoclick compound in the popular PQ-ERA reaction through strategic molecular substitution. They now report a superb photoreaction quantum yield, high reaction rates and notable oxygen tolerance.

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New work could help forest managers predict which forests are most at risk from drought and which will survive.

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Machine learning model provides quick method for determining the composition of solid chemical mixtures using only photographs of the sample.

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Researchers have developed a miniature battery that could be used to power tiny devices integrated into human tissues. The design uses an ionic gradient across a chain of droplets -- inspired by how electric eels generate electricity. The device was able to regulate the biological activity of human neurons. This could open the way to the development of tiny bio-integrated devices, with a range of applications in biology and medicine.

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A new article found that overhunting of gorillas, elephants, and other large fruit-eating seed-dispersers make tropical forests less able to store or sequester carbon.

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An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.

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Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.

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Researchers have implemented a quantum-based method to observe a quantum effect in the way light-absorbing molecules interact with incoming photons. Known as a conical intersection, the effect puts limitations on the paths molecules can take to change between different configurations. The observation method makes use of a quantum simulator, developed from research in quantum computing, and offers an example of how advances in quantum computing are being used to investigate fundamental science.

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Scientists have developed a new method for detecting mid-infrared (MIR) light at room temperature using quantum systems.

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Using a trapped-ion quantum computer, the research team witnessed the interference pattern of a single atom caused by a 'conical intersection'. Conical intersections are known throughout chemistry and are vital to rapid photo-chemical processes such as light harvesting in human vision or photosynthesis.

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A study on 'canopy soils' on old trees in Costa Rica shows they are important habitats and carbon stores that cannot easily be replaced.

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Researchers have made a significant breakthrough in the field of asymmetric synthesis of beta-lactams, which are prominent in bioactive compounds. Their innovative approach employs nickel and hydrocarbon sources that are abundant on Earth to access value-added beta-lactam products. The employment of nickel-hydride catalysis and alkenyl dioxazolone derivatives gives rise to the selective formation of four-membered lactam products.

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A team of chemists have developed a novel concept in which a mixture of molecules that behave like mirror images is converted to a single form. To this end, they use light as external energy source. The conversion is relevant e.g. for the preparation of drugs.

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A new study of cavity-nesting birds in Ecuador shows the influence of deforestation on their habitat and reproductive success. Nest boxes could help.

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A research group has established key early steps in the conversion of aromatic molecules, a major constituent of traffic and other urban volatile emissions, into aerosol. Their findings increase understanding of the chemical processes that degrade urban air quality and influence climate change.

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Climate impacts such as dry, hot summers reduce the growth and increase the mortality of trees in the Black Forest because they negatively influence the climatic water balance, i.e., the difference between precipitation and potential evapotranspiration. That is the central finding of a long-term study of the influence of climate and climate change on trees in the Black Forest.

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Researchers have designed a new type of quantum computer that uses fermionic atoms to simulate complex physical systems. The processor uses programmable neutral atom arrays and is capable of simulating fermionic models in a hardware-efficient manner using fermionic gates. The team demonstrated how the new quantum processor can efficiently simulate fermionic models from quantum chemistry and particle physics.

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Researchers combined human and ecological factors to analyze the global scale of non-native tree species invasions. Human activity in hotspots of global trade, such as maritime ports, is linked to an increased likelihood of non-native tree species invasions. However, a high diversity of native tree species can help to curb the intensity of such invasions.

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If coal and natural gas power generation were 2% more efficient, then, every year, there could be 460 million fewer tons of carbon dioxide released and 2 trillion fewer gallons of water used. A recent innovation to the steam cycle used in fossil fuel power generation could achieve this.

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A research team enhanced hydrogen evolution catalyst through stepwise deposition.