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Categories: Chemistry: Organic Chemistry, Ecology: Sea Life

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C-H activation-based method should speed drug molecule design and diversification.

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Sea otters are one of the few animals that use tools to access their food, and a new study has found that individual sea otters that use tools -- most of whom are female -- are able to eat larger prey and reduce tooth damage when their preferred prey becomes depleted.

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A team of chemists has achieved a significant breakthrough in the field of chemical synthesis, developing a novel method for manipulating carbon-hydrogen bonds. This groundbreaking discovery provides new insights into the molecular interactions of positively charged carbon atoms. By selectively targeting a specific C--H bond, they open doors to synthetic pathways that were previously closed -- with potential applications in medicine.

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Vanilla, the most widely used flavoring compound in confectionaries and cosmetics, gets its sweet flavor and aroma from the chemical compound -- 'vanillin'. However, the large-scale production of natural vanillin is impeded by the lack of microbial processes and enzymes which can commercially generate vanillin. Now, researchers have genetically engineered a novel enzyme which can convert ferulic acid from plant waste into vanillin in a one-step sustainable process.

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Scientists have discovered that colonies of gelatinous sea animals swim through the ocean in giant corkscrew shapes using coordinated jet propulsion, an unusual kind of locomotion that could inspire new designs for efficient underwater vehicles.

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A new study has confirmed a long-held assumption: that orcas take just one breath between dives. The researchers used drone footage and biological data from tags suction-cupped to 11 northern and southern resident killer whales off the coast of B.C. to gather information on the animals' habits. Confirming orcas take only one breath between dives allowed the researchers to calculate how many litres of oxygen adults and juveniles consume per minute. This provides another piece of the puzzle in estimating orca energy expenditure, and eventually, how many fish the animals need to eat per day, key to their conservation.

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The optimal design of a novel zeolite catalyst enables tandem reaction that turns greenhouse gases into value-added chemicals, report scientists. By tuning the separation between different active sites on the catalyst, they achieved the stepwise conversion of methane into methanol and then to hydrocarbons at mild conditions. These findings will help reduce energy costs and greenhouse gas emissions across various industrial fields.

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'Dust clouds' at the bottom of the deep sea, that will be created by deep-sea mining activities, descend at a short distance for the biggest part. Yet, a small portion of the stirred-up bottom material remains visible in the water at long distances.

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In the emperor penguin courtship call, male vocalizations are composed of long, slow bursts with lower frequency tones than the female version. But calls of SeaWorld San Diego male penguin E-79 defied this binary. Also unusual was this penguin's male companion, E-81. The pair 'kept company' and sometimes exhibited ritual courtship displays. Researchers studied the courtship calls of E-79 and E-81, recording the birds in their below-freezing enclosure and refining the usual technique for analyzing the bursts.

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Semiconductors are the foundation of all modern electronics. Now, researchers have developed a new method where organic semiconductors can become more conductive with the help of air as a dopant. The study is a significant step towards future cheap and sustainable organic semiconductors.

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Researchers who contributed to the development of record-breaking solar cells a few years ago, expanded their invention. The self-assembled monolayers can now be applied not only in inverted but also in regular structure perovskite solar cells.

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Scientists are one step closer to combating coral-destroying crown-of-thorns starfish, following a study into the pest's genetics.

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Heavily-used shipping lanes that pass through whale shark feeding grounds pose a threat to the species, according to scientists who have revealed areas where the creatures are at the highest risk.

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A battery made from zinc and lignin that can be used over 8000 times. This has been developed with a vision to provide a cheap and sustainable battery solution for countries where access to electricity is limited.

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A young whale's journey across the Mediterranean highlights the many threats facing ocean animals, researchers say.

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Polystyrene is made from styrene building blocks and is the most widely used plastic in terms of volume, for example in packaging. Unlike PET, which can now be produced and recycled using biotechnological methods, the production of polystyrene has so far been a purely chemical process. The plastic can't be broken down by biotechnological means, either. Researchers are looking for ways to rectify this: An international team decoded a bacterial enzyme that plays a key role in styrene degradation. This paves the way for biotechnological application.

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Researchers have used a novel combination of short-read and long-read RNA sequencing to identify the different isoforms of genes expressed in the crustacean Daphnia magna. Males and females are genetically identical, but using this technique the team revealed genes that switch the predominant isoform in a male-female-dependent manner. This study may help further advance technologies in crustacean aquaculture.

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A research team has discovered how carboxysomes, carbon-fixing structures found in some bacteria and algae, work. The breakthrough could help scientists redesign and repurpose the structures to enable plants to convert sunlight into more energy, paving the way for improved photosynthesis efficiency, potentially increasing the global food supply and mitigating global warming.

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A method has been discovered to treat water heavily contaminated with unhealthful forever chemicals, known by chemists as PFAS or poly- and per-fluoroalkyl substances. It involves treating heavily contaminated water with ultraviolet (UV) light, sulfite, and a process called electrochemical oxidation. It breaks up strong fluorine-to-carbon bonds in the PFAS compounds and other concentrated organic compounds in heavily polluted water. The reaction also occurs at room temperature without a need for additional heat or high pressure. This method is expected to be useful in cleanups of PFAS pollution from decades of fire suppressant foam use at military facilities.

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An international collaboration says the world's largest marine protected areas aren't collectively delivering the biodiversity benefits they could be because of slow implementation of management strategies and a failure to restrict the most impactful human activities.