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Categories: Chemistry: General, Environmental: Wildfires
Published Chemical synthesis: New strategy for skeletal editing on pyridines
(via sciencedaily.com) Original source A team has introduced a strategy for converting carbon-nitrogen atom pairs in a frequently used ring-shaped compound into carbon-carbon atom pairs. The method has potential in the quest for active ingredients for new drugs, for example.
Published Lighting the path: Exploring exciton binding energies in organic semiconductors
(via sciencedaily.com) Original source Organic semiconductors are materials that find applications in various electronic devices. Exciton binding energy is an important attribute that influences the behavior of these materials. Now, researchers have employed advanced spectroscopic techniques to accurately determine these energies for various organic semiconductor materials, with a high precision of 0.1 electron volts. Their study reveals unexpected correlations that are poised to shape the future of organic optoelectronics, influence design principles, and find potential applications in bio-related materials.
Published Next-generation batteries could go organic, cobalt-free for long-lasting power
(via sciencedaily.com) Original source In the switch to 'greener' energy sources, the demand for rechargeable lithium-ion batteries is surging. However, their cathodes typically contain cobalt -- a metal whose extraction has high environmental and societal costs. Now, researchers in report evaluating an earth-abundant, carbon-based cathode material that could replace cobalt and other scarce and toxic metals without sacrificing lithium-ion battery performance.
Published Efficiently moving urea out of polluted water is coming to reality
(via sciencedaily.com) Original source Researchers have developed a material to remove urea from water and potentially convert it into hydrogen gas. By building these materials of nickel and cobalt atoms with carefully tailored electronic structures, the group has unlocked the potential to enable these transition metal oxides and hydroxides to selectively oxidize urea in an electrochemical reaction. The team's findings could help use urea in waste streams to efficiently produce hydrogen fuel through the electrolysis process, and could be used to sequester urea from water, maintaining the long-term sustainability of ecological systems, and revolutionizing the water-energy nexus.
Published Cobalt-free batteries could power cars of the future
(via sciencedaily.com) Original source A new battery material could offer a more sustainable way to power electric cars. The lithium-ion battery includes a cathode based on organic materials, instead of cobalt or nickel.
Published Chemists create a 2D heavy fermion
(via sciencedaily.com) Original source Researchers have synthesized the first 2D heavy fermion. The material, a layered intermetallic crystal composed of cerium, silicon, and iodine (CeSiI), has electrons that are 1000x heavier and is a new platform to explore quantum phenomena.
Published Let it glow: Scientists develop new approach to detect 'forever chemicals' in water
(via sciencedaily.com) Original source Researchers have created a new way to detect 'forever chemical' pollution in water, via a luminescent sensor.
Published Artificial 'power plants' harness energy from wind and rain
(via sciencedaily.com) Original source Fake plants are moving into the 21st century! Researchers developed literal 'power plants' -- tiny, leaf-shaped generators that create electricity from a blowing breeze or falling raindrops. The team tested the energy harvesters by incorporating them into artificial plants.
Published Study reveals a reaction at the heart of many renewable energy technologies
(via sciencedaily.com) Original source Chemists have mapped how proton-coupled electron transfers happen at the surface of an electrode. Their results could help researchers design more efficient fuel cells, batteries, or other energy technologies.
Published Squishy, metal-free magnets to power robots and guide medical implants
(via sciencedaily.com) Original source 'Soft robots,' medical devices and implants, and next-generation drug delivery methods could soon be guided with magnetism -- thanks to a metal-free magnetic gel developed by researchers. Carbon-based, magnetic molecules are chemically bonded to the molecular network of a gel, creating a flexible, long-lived magnet for soft robotics.
Published Cheap substitute for expensive metal in an industrially common chemical reaction
(via sciencedaily.com) Original source Researchers have helped minimize the cost of an important class of chemical transformations: converting nitriles into primary amines. Their experimental protocol uses a cheap nickel catalyst instead of an expensive noble metal, is convenient to conduct, and works for a broad range of starting materials. This work is an important advance in sustainable chemistry that might help lower the cost of producing nylon and many other everyday products.
Published Water molecule discovery contradicts textbook models
(via sciencedaily.com) Original source Textbook models will need to be re-drawn after a team of researchers found that water molecules at the surface of salt water are organised differently than previously thought.
Published The power of pause: Controlled deposition for effective and long-lasting organic devices
(via sciencedaily.com) Original source In organic optoelectronic devices, the control of molecular deposition on thin films is important for optimal surface arrangement and device performance. In a recent study, researchers developed a new method for achieving stable deposition on thin films effectively. They also developed a tool to track real-time potential changes on the surface. These findings are expected to aid the improvement of organic devices, such as organic light-emitting diodes, in terms of efficacy and durability.
Published Core-shell 'chemical looping' boosts efficiency of greener approach to ethylene production
(via sciencedaily.com) Original source Oxidative coupling of methane (OCM) is now one step closer to leaving the lab and entering the real world. Researchers have developed an OCM catalyst that exceeds 30 percent when it comes to the production of ethylene.
Published New catalytic technique creates key component of incontinence drug in less time
(via sciencedaily.com) Original source Researchers have developed a unique catalyst that promises to revolutionize drug synthesis. It overcomes a common problem associated with the production of drugs from ketones. Using their catalyst, the researchers synthesized a key component of the commonly used incontinence drug oxybutynin. Their results underscore the potential of the catalyst to improve drug discovery and development.
Published Capturing greenhouse gases with the help of light
(via sciencedaily.com) Original source Researchers use light-reactive molecules to influence the acidity of a liquid and thereby capture of carbon dioxide. They have developed a special mixture of different solvents to ensure that the light-reactive molecules remain stable over a long period of time. Conventional carbon capture technologies are driven by temperature or pressure differences and require a lot of energy. This is no longer necessary with the new light-based process.
Published Spying on a shape-shifting protein
(via sciencedaily.com) Original source Researchers are using crystallography to gain a better understanding of how proteins shapeshift. The knowledge can provide valuable insight into stopping and treating diseases.
Published Bulky additives could make cheaper solar cells last longer
(via sciencedaily.com) Original source An insight into preventing perovskite semiconductors from degrading quickly could help enable solar cells estimated to be two to four times cheaper than today's thin-film solar panels.
Published Molecularly designing polymer networks to control sound damping
(via sciencedaily.com) Original source The world is filled with a myriad of sounds and vibrations -- the gentle tones of a piano drifting down the hall, the relaxing purr of a cat laying on your chest, the annoying hum of the office lights. Imagine being able to selectively tune out noises of a certain frequency. Researchers have now synthesized polymer networks with two distinct architectures and crosslink points capable of dynamically exchanging polymer strands to understand how the network connectivity and bond exchange mechanisms govern the overall damping behavior of the network. The incorporation of dynamic bonds into the polymer network demonstrates excellent damping of sound and vibrations at well-defined frequencies.
Published Towards realizing eco-friendly and high-performance thermoelectric materials
(via sciencedaily.com) Original source In a new study, environmentally benign inverse-perovskites with high energy conversion efficiency have been reported by scientists with potential for practical application as thermoelectric materials (TEMs). Addressing the limitations typically faced with TEMs, such as insufficient energy conversion efficiency and environmental toxicity due to heavy elements, the new TEMs provide a suitable alternative to TEMs based on toxic elements with better thermoelectric properties than conventional eco-friendly TEMs.