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Categories: Chemistry: General, Offbeat: Earth and Climate
Published New bio-based glues form adhesive bonds that grow stronger in water
(via sciencedaily.com) Patent-pending adhesive formulations developed from fully sustainable, bio-based components establish bonds that grow stronger when underwater or exposed to wet conditions.
Published Extending the playing field for organosulfurs: a new way to synthesize sulfinate esters
(via sciencedaily.com) Sulfinate esters, a type of organosulfur compounds, are typically synthesized using thiols. However, these substances are difficult to work with due to their unpleasant smell and oxidizability in air. Now, a research team has found a way to produce sulfinate esters through the direct oxidation of thioesters, which are easily accessible and stable. Their findings will help expand the field of organosulfur chemistry and hopefully lead to new applications in pharmaceuticals.
Published Chemists devise a method for C-H activation of alcohols
(via sciencedaily.com) Chemists have extended a powerful molecule-building method -- called C-H activation -- to the broad class of chemicals known as alcohols.
Published Researchers develop highly efficient and stable photoelectrode for water splitting using organic semiconductors
(via sciencedaily.com) A recent study has unveiled a significant breakthrough in photoelectrode development.
Published Fossil spines reveal deep sea's past
(via sciencedaily.com) Original source Right at the bottom of the deep sea, the first very simple forms of life on earth probably emerged a long time ago. Today, the deep sea is known for its bizarre fauna. Intensive research is being conducted into how the number of species living on the sea floor have changed in the meantime. Some theories say that the ecosystems of the deep sea have emerged again and again after multiple mass extinctions and oceanic upheavals. Today's life in the deep sea would thus be comparatively young in the history of the Earth. But there is increasing evidence that parts of this world are much older than previously thought.
Published Electrifying heavy-duty vehicles could reduce environmental inequalities
(via sciencedaily.com) If the region surrounding Chicago -- North America's largest freight hub -- shifted just 30% of its current on-road heavy-duty vehicles to electric versions, it would substantially reduce pollution and save hundreds of lives per year, with the benefits largely concentrated in disadvantaged communities, according to a new study. The study authors highlight that neighborhoods with predominantly Black, Hispanic and Latinx residents would benefit the most -- potentially reducing disproportionate pollution and health burdens in historically marginalized areas.
Published New ribozyme can make RNA molecules accessible for click chemistry in living cells
(via sciencedaily.com) Important progress for RNA research: A team has discovered a new ribozyme that can label RNA molecules in living cells.
Published Bit by bit, microplastics from tires are polluting our waterways
(via sciencedaily.com) Urban stormwater particles from tire wear were the most prevalent microplastic a new study has found. The study showed that in stormwater runoff during rain approximately 19 out of every 20 microplastics collected were tire wear particles with anywhere from 2 to 59 particles per liter of water. Tire rubber contains up to 2500 chemicals with the contaminants that leach from tires considered more toxic to bacteria and microalgae than other plastic polymers.
Published Novel titanium dioxide catalyst support for electrocatalytic carbon dioxide reduction
(via sciencedaily.com) Carbon dioxide can be electrocatalytically reduced to useful resources using conventional catalysts such as gold or lead supported on conductive carbon. However, the high pH environment near electrodes often degrades the catalyst support, rendering them ineffective. Now, researchers have developed novel in-liquid plasma-treated titanium dioxide electrode decorated with silver nanoparticles as an alternate catalyst support, facilitating enhanced conversion of carbon dioxide to useful products, such as syngas, a clean alternative to fossil fuels.
Published Efficient and mild: Recycling of used lithium-ion batteries
(via sciencedaily.com) Lithium-ion batteries (LIBs) provide our portable devices like tablets and mobiles -- and increasingly also vehicles -- with power. As the share of volatile renewable energy needing electricity storage increases, more and more LIBs are needed, lithium prices rise, resources dwindle, and the amount of depleted batteries that contain toxic substances increases. Researchers introduce a novel approach for the recovery of lithium from used LIBs.
Published 3D-printed 'living material' could clean up contaminated water
(via sciencedaily.com) A 'living material,' made of a natural polymer combined with genetically engineered bacteria, could offer a sustainable and eco-friendly solution to clean pollutants from water. Researchers developed their living material using a seaweed-based polymer and bacteria that have been programmed to produce an enzyme that transforms various organic pollutants into harmless compounds. In tests, heir material decontaminated water solutions tainted with a pollutant from textile manufacturing: indigo carmine, a blue dye that is used to color denim.
Published Striking gold with molecular mystery solution for potential clean energy
(via sciencedaily.com) Hydrogen spillover is exactly what it sounds like. Small metal nanoparticles anchored on a thermally stable oxide, like silica, comprise a major class of catalysts, which are substances used to accelerate chemical reactions without being consumed themselves. The catalytic reaction usually occurs on the reactive -- and expensive -- metal, but on some catalysts, hydrogen atom-like equivalents literally spill from the metal to the oxide. These hydrogen-on-oxide species are called 'hydrogen spillover.'
Published A step closer to digitizing the sense of smell: Model describes odors better than human panelists
(via sciencedaily.com) A main crux of neuroscience is learning how our senses translate light into sight, sound into hearing, food into taste, and texture into touch. Smell is where these sensory relationships get more complex and perplexing. To address this question, a research team are investigating how airborne chemicals connect to odor perception in the brain. They discovered that a machine-learning model has achieved human-level proficiency at describing, in words, what chemicals smell like.
Published Growing triple-decker hybrid crystals for lasers
(via sciencedaily.com) By controlling the arrangement of multiple inorganic and organic layers within crystals using a novel technique, researchers have shown they can control the energy levels of electrons and holes (positive charge carriers) within a class of materials called perovskites. This tuning influences the materials' optoelectronic properties and their ability to emit light of specific energies, demonstrated by their ability to function as a source of lasers.
Published Taking photoclick chemistry to the next level
(via sciencedaily.com) Researchers have been able to substantially improve photoclick chemistry. They were able to boost the reactivity of the photoclick compound in the popular PQ-ERA reaction through strategic molecular substitution. They now report a superb photoreaction quantum yield, high reaction rates and notable oxygen tolerance.
Published Surpassing the human eye: Machine learning image analysis rapidly determines chemical mixture composition
(via sciencedaily.com) Machine learning model provides quick method for determining the composition of solid chemical mixtures using only photographs of the sample.
Published Direct formation of sulfuric acid in the atmosphere
(via sciencedaily.com) In the atmosphere, gaseous sulfuric acid can form particles that influence the physical properties of clouds. Thus, the formation of sulfuric acid in the gas phase directly affects the radiative forcing and Earth's climate. In addition to the known formation from sulfur dioxide, researchers have now been able to demonstrate through experiments that there is another formation pathway that has been speculated about for decades. Sulfuric acid in the atmosphere can also be formed directly by the oxidation of organic sulfur compounds. This new production pathway can be responsible for up to half of the gaseous sulfuric acid formation over the oceans and is thus of high importance for climate projections -- especially over the oceans of the Southern Hemisphere.
Published New 'droplet battery' could pave the way for miniature bio-integrated devices
(via sciencedaily.com) Researchers have developed a miniature battery that could be used to power tiny devices integrated into human tissues. The design uses an ionic gradient across a chain of droplets -- inspired by how electric eels generate electricity. The device was able to regulate the biological activity of human neurons. This could open the way to the development of tiny bio-integrated devices, with a range of applications in biology and medicine.
Published A lightweight wearable device helps users navigate with a tap on the wrist
(via sciencedaily.com) Original source Scientists have developed a fabric-based wearable device that 'taps' a user's wrist with pressurized air, silently helping them navigate to their destination. The study demonstrated that users correctly interpreted which direction the device was telling them to go an average of 87% of the time. Since the wearable embeds most of its control system within the fabric itself, using air instead of electronics, it can be built lighter and more compact than existing designs.
Published Overcoming the challenges to synthesising iron--sulfur proteins outside the glovebox
(via sciencedaily.com) Iron--sulfur (Fe--S) proteins, essential to all life forms, are difficult to synthesise due to the complicated molecular machinery involved and sensitivity of Fe--S clusters to oxygen. In a new study, a team of researchers devised an innovative protocol for synthesising mature Fe--S proteins, by bringing together a recombinant sulfur assimilation (SUF) system and an oxygen-scavenging system, thereby, paving the way for new technologies and a better understanding of the evolution of life.